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Synthesis of meso-2,2’-bipyridyl-substituted calix[4]arenes and their response to metal cations
Abstract
A convenient synthetic approach to meso-substituted with 2,2’-bipyridine and 1-(pyridin-2-yl)isoquinoline residues calix[4]arenes is reported. This approach involves the reaction of generated in situ 2-lithio-calix[4]arene with 1,2,4-triazine precursor with the following aromatization of the obtained adduct, and the aza-Diels-Alder reaction of the 1,2,4-triazinyl-substituted calix[4]arene with 2,5-norbornadien or in-situ generated 1,2-dehydrobenzene. The UV/fluorescence response of thus obtained meso-pyridyl-substituted calix[4]arenes to metal cations is studied.
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DOI: https://doi.org/10.15826/chimtech.2020.7.4.14
Copyright (c) 2020 Moseev T.D., Khasanov A.F., Varaksin M.V., Kopchuk D.S., Kovalev I.S., Taniya O.S., Rahman M., Santra S., Zyryanov G.V., Chupakhin O.N., Charushin V.N.
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