Subsolidus phase equilibria of the CuO – SrO – ZnO pseudoternary system in air at 900 °C

J.-C. Grivel

doi:10.15826/chimtech.2018.5.1.01

Subsolidus phase equilibria of the CuO – SrO – ZnO pseudoternary system in air at 900 °C

J.-C. Grivel

Abstract

The subsolidus phase equilibria of the CuO – SrO – ZnO system were determined at 900 °C in air. The pseudoternary section does not contain ternary oxide phases but is made of 5 three-phase regions and 2 narrow two-phase regions linked to a Sr₁₄Cu_24-xZn_xO_41-y solid solution. The maximum solubility of Zn in this phase is limited to x ≈ 0.1, but this low doping level results in a significant decrease of the electrical resistivity by about one order of magnitude compared to the undoped compound. The other binary oxide phases SrZnO₂,Sr₂CuO₃, and SrCuO₂ do not form solid solutions extending into the ternary system. SrZnO₂ was found to decompose upon contact with ambient air.

Keywords

phase equilibria; isothermal section; oxide systems; pseudoternary; CuO; SrO; ZnO; spin-ladder; electrical resistivity

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References

Bednorz JG, Muller KA. Possible high-Tc superconductivity in the Ba-La-Cu-O system. Zeitschrift für Physik. 1986;B64:189–93. doi:10.1007/BF01303701

Grivel JC. Subsolidus phase relations of the CaO – REOx – CuO systems (RE = Eu, Tb, Dy, Ho, Er, Lu and Sc) at 900°C in air. J Phase Equilib Diffus. 2016;37:601–10. doi:10.1007/s11669-016-0489-4

Zhuravlev VD, Velikodnyi YA, Kristallov LV. Study of phase-equilibria in the CuO – SrO – V2O5 system. Zh Neorg Khim. 1987;32:3060–3.

Drozdova NM, Sirotinkin VP, Evdokimov AA. Phase correlations in subsolidus domain of SrO – CuO – Nb2O5 system. Zh Neorg Khim. 1991;36:1588–9.

Sirotinkin VP, Drozdova NM. Phase relations in SrO – CuO – Nb2O5 system in the spectrum with high strontium oxide content. Zh Neorg Khim. 1993;38:1912–3.

Yang LT, Liang JK, Song GB, Chang H, Rao GH. Compounds and phase relations in the SrO – Fe2O3 – CuO, SrO – Fe2O3 – Gd2O3 and Gd2O3 – Fe2O3 – CuO ternary systems. J Alloys Compd. 2003;353:301–6. doi:10.1016/S0925-8388(02)01301-4

Lee SY, Kim HE, Yoo SI. Subsolidus phase relations in the SrO – CuO – TiO2 ternary system at 950°C in air. J Alloys Compd. 2013:556:210–3. doi:10.1016/j.jallcom.2012.11.193

Grivel JC. Subsolidus phase relations of the SrO – MO2 – CuO systems ( M = Ti, Zr and Hf) at 900 °C in air. J Alloys Compd. 2008;464:457–60. doi:10.1016/j.jallcom.2007.10.013

Grivel JC. Subsolidus phase relations of the SrO – Ta2O5 – CuO system at 900°C in air. J Alloys Compd. 2009;486:293–8. doi:10.1016/j.jallcom.2009.06.133

Grivel JC. Subsolidus phase relations of the SrO – WO3 – CuO system at 800°C in air. J Alloys Compd. 2012;513:304–9. doi:10.1016/j.jallcom.2011.09.104

Grivel JC. Subsolidus phase relations of the CoOx – CuO – SrO system. J Phase Equilib Diffus. 2017;38:646–55. doi:10.1007/s11669-017-0581-4

Srivastava A, Kumar N, Misra KP, Khare S. Enhancement of band gap of ZnO nanocrystalline films at a faster rate using Sr dopant. Electron Mater Lett. 2014;10:703–11. doi:10.1007/s13391-014-3131-9

Vijaran TA, Chandramohan R, Varanarasu S, Thirumalai J, Subramanian SP. J Mater Sci. 2008;43:1776–82. doi:10.1007/s10853-007-2404-1

Harish S, Sabarinathan M, Archana J, Navaneethan M, Nisha KD, Ponnusamy S, Gupta V, Muthamizhchelvan C, Aswal DK, Ikeda H, Hayakawa Y. Synthesis of ZnO/SrO nanocomposites for enhanced photocatalytic activity under visible light irradiation. Appl Surf Sci. 2017;418:147–55. doi:10.1016/j.apsusc.2017.01.164

Das T, Das BK, Parashar K, Kumar R, Choudhary HK, Anupama AV, Sahoo B, Sahoo PK, Parashar SKS. Effect of Sr-doping on sinterability, morphology, structure, photocatalytic activity and AC conductivity of ZnO ceramics. J Mater Sci: Mater Electron. 2017;28:13587–95. doi:10.1007/s10854-017-7198-6

Güntürkün K, Toplan Ö. Densification and grain growth of SrO-doped ZnO. Ceramics – Silikáty. 2006;50:225–31.

Sharma PS, Dutta RK, Pandey AC, Doping dependent room-temperature ferromagnetism and structural properties of dilute magnetic semiconductor ZnO:Cu2+ nanorods. J Magn Magn Mater. 2009;321:4001–5. doi:10.1006/j.jmmm.2009.07.066

Liu HL, Yang JH, Zhang YJ, Wang YX, Wei MB, Wang DD, Zhao LY, Lang JH, Gao M. Ferromagnetism in Cu-doped ZnO nanoparticles at room temperature. J Mater Sci: Mater Electron. 2009;20:628–31. doi:10.1007/s10854-008-9776-0

Harish S, Archana J, Sabarinathan M, Navaneethan M, Nisha KD, Ponnusamy S, Muthamizhchelvan C, Ikeda H, Aswal DK, Hayakawa Y. Controlled structural and compositional characteristic of visible light active ZnO/CuO photocatalyst for the degradation of organic pollutants. Appl Surf Sci. 2017;418:103–12. doi:10.1016/j.apsusc.2016.12.082

Geng LL, Han CH, Zhang D. Catalysis investigation of PET depolymerization by ZnSrO2 under microwave irradiation. Adv Mater. 2011;239–42:3194–7. doi:10.4028/www.scientific.net/AMR.239-242.3194

Yang HK, Lee JH, Hong WT, Jang HI, Moon BK, Jeong JH and Je JY. Preparation and photoluminescence properties of nano-sized SrZnO2:Sm3+ phosphor powders obtained by high-energy ball milling. Ceram Int. 2015;41:991–4. doi:10.1016/j.ceramint.2014.09.019

Manavbasi A, LaCombe JC. A new blue-emitting phosphor, SrZnO2:Pb2+, synthesized by the adipic templated gel route. J Lumin. 2007;128:129–34. doi:10.1016/j.jlumin.2007.06.002

Maeda H, Tanaka Y, Fukutomi M, Asano T, Togano K, Kumakura H, Uehara M, Ikeda S, Ogawa K, Horiuchi S, Matsui Y. New high-Tc superconductors without rare-earth element. Physica C. 1988;153–5:602–7. doi:10.1016/0921-4534(88)90727-7

Sheng ZZ, Hermann AM, Bulk superconductivity at 120K in the Tl-Ca/Ba-Cu-O system. Nature. 1988;332:138–9. doi:10.1038/332138a0

McMurdie H, Morris M, Evans E, Paretzkin B, Wong-Ng W, Ettlinger L, Hubbard C. JCPDS reference pattern 36-1451.

Modwi A, Lemine OM, Alshammari M, Houas A. Ferromagnetism at room temperature in Zn0.95Cu0.05O nanoparticles synthesized by sol-gel method. Mater Lett. 2017;194:98–101. doi:10.1016/j.matlet.2017.02.029

Garces NY, Wang L, Bai L, Giles NC, Halliburton LE, Cantwell G. Role of copper in the green luminescence from ZnO crystals. Appl Phys Lett. 2002;81:622–4. doi:10.1063/1.1494125

Borzi RA, Stewart SJ, Punte G, Mercader RC, Zysler RD, Tovar M, History-dependent magnetic properties in pure and Zn-doped cupric oxide. Solid State Commun. 2001;117:311–4. doi:10.1016/S0038-1098(00)00467-1

Prabhakaran D, Boothroyd AT. Single crystal growth of Zn-doped CuO by the floating-zone method. J Cryst Growth. 2003;250:77–82. doi:10.1016/S0022-0248(02)02230-3

Buchmeier W, Lutz HD. Crystal-structures of Sr(OH)2·H2O, Ba(OH)2·H2O (O-RH and MON) and Ba(OH)2.3·H2O. Z Anorg Allg Chem. 1986;538:131–42. doi:10.1002/zaac.19865380713

Liang JK, Zhan C, Fei W, Xie SS. Phase-diagram of SrO – CaO – CuO ternary-system. Solid State Commun. 1990;75:247–52. doi:10.1016/0038-1098(90)90279-K

Kosmynin AS, Slobodin BV, Balashov VL, Garkushin IK, Fotiev AA, Trunin AS. Phase-equilibria in the CaO-SrO-CuO system (≥ 70 mol % CuO). Inorg Mater. 1995;7:867–70.

Hwang NM, Roth RS, Rawn CJ. Phase-equilibria in the systems SrO-CuO and SrO-1/2Bi2O3. J Am Ceram Soc. 1990;73:2531–3. doi:10.1111/j.1151-2916.1990.tb07628.x

Suzuki RO, Bohac P, Gauckler LJ. Thermodynamics and phase-equilibria in the Sr-Cu-O system. J Am Ceram Soc. 1992;75:2833–42. doi:10.1111/j.1151-2916.1992.tb05513.x

Nevřiva M, Kraus H. Study of phase-equilibria in the partially open Sr-Cu-(O) system. Physica C. 1994;235–40:325–6. doi:10.1016/0921-4534(94)91386-2

Alcock CB, Li BZ. Thermodynamic study of the Cu-Sr-O system. J Am Ceram Soc. 1990;73:1176–80. doi:10.1111/j.1151-2916.1990.tb05176.x

De Leeuw DM, Mutsaers CAHA, Geelen GPJ, Smoorenburg HCA, Langereis C. Compounds and phase compatibilities in the system Y2O3 – (BaO) – SrO – CuO at 950 °C. Physica C. 1988;152:508–12. doi:10.1016/0921-4534(88)90061-5

Wu F, Xie S, Chen Z, Ling JK. Subsolidus phase-relations of the Y2O3 – SrO – CuO system. J Mater Sci. 1992;27:3082–4. doi:10.1007/BF01154122

Roth RS, Rawn CJ, Whitler JD, Chiang CK, Wong-Ng W. Phase-equilibria and crystal-chemistry in the quaternary system Ba-Sr-Y-Cu-O in air. J Am Ceram Soc. 1989;72:395–9. doi:10.1111/j.1151-2916.1989.tb06142.x

De Leeuw DM, Mutsaers CAHA, Geelen GPJ, Langereis C. Compounds and phase compatibilities in the system La2O3 – SrO – CuO at 950 °C. J Solid State Chem. 1989;80:276–85. doi:10.1016/0022-4596(89)90090-X

Chen X, Liang JK, Wang C, Rao GH, Xing XR, Song ZH, Qiao ZY. The Nd2O3 – SrO – CuO system – compounds and phase-relations. J Alloys Compd. 1994;205:101–6. doi:10.1016/0925-8388(94)90773-0

Han CQ, Chen XL, Liang JK, Liu QL, Rao GH. The ternary system Sm2O3 – SrO – CuO: compounds and phase relations. J Alloys Compd. 200;314:301–4. doi:10.1016/S0925-8388(00)01255-X

Han CQ, Chen XL, Liang JK, Liu QL, Rao GH. The ternary system Eu2O3 – SrO – CuO: compounds and phase relations. J Solid State Chem. 2001;156:247–50. doi: 10.1006/jssc.2000.8997

Han CQ, Gao Y, Chen XL, Liang JK, Rao H. The ternary system Gd2O3 – SrO – CuO: compounds and phase relations. J Alloys Compd. 2001;321:54–9. doi:10.1016/S0925-8388(01)00873-8

Wong-Ng W, Huang Q, Levin I, Kaduk JA, Dillingham J, Haugan T, Suh J, Cook LP. Crystal chemistry and phase equilibria of selected SrO – R2O3 – CuOx and related systems; R = lanthanides and yttrium. Int J Inorg Mater. 2001;3:1283–90. doi:10.1016/S1466-6049(01)00133-7

Wong-Ng W, Dillingham J, Cook LP. Phase relations of the SrO – Ho2O3 – CuOx system. J Solid State Chem. 2000;149:333–7. doi:10.1006/jssc.1999.8536

Grivel JC, Andersen NH. Subsolidus phase relations of the SrO – Er2O3 – CuO system. J Alloys Compd. 2005;389:186–9. doi:10.1016/j.jallcom.2004.05.086

Han CQ, Chen XL, Liang JK, Liu QL, Chen Y, Rao GH. The ternary system Tm2O3 – SrO – CuO: compounds and phase relations. J Alloys Compd. 2000;309:95–9. doi:10.1016/S0925-8388(00)01041-0

Dillingham J, Wong-Ng W, Levin I. Phase equilibria of the SrO – Yb2O3 – CuOx system in air. Int J Inorg Mater. 2001;3:569–73. doi:10.1016/S1466-6049(01)00015-0

Grivel JC, Andersen NH. Subsolidus phase relations of the SrO – RE2O3 – CuO systems (RE = Tm, Lu and Sc). J Alloys Compd. 2005;391:292–5. doi:10.1016/j.jallcom.2004.08.077

Grivel JC, Andersen NH. Subsolidus phase relations of the SrO – REOx – CuO systems (RE = Ce, Pr and Tb). J Alloys Compd. 2007;436:261–5. doi:10.1016/j.jallcom.2006.07.020

DOI: https://doi.org/10.15826/chimtech.2018.5.1.01

Copyright (c) 2017 Jean-Claude Grivel

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