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Methyl orange sorption on octadecylamine-modified iron oxide magnetic nanoparticles

Liang Tianhui, Sayara Aga-Tagieva, Alexander Omelyanchik, Zhang Xiaozhou, Hong Lu, Katerina Levada, Valeria Rodionova, Kurban Magomedov

Abstract


This study investigates the sorption of 2-methyl orange dye onto octadecylamine-modified iron oxide magnetic nanoparticles (ODA-IONPs). The synthesized ODA-IONPs exhibit remarkable sorption capacity, reaching 800 mg/g at the nanoparticle concentrations ranging from 5 to 10 mg/g and pH of 2–8. The sorption process demonstrates rapid kinetics, achieving 90% of maximum sorption within 0.5 min. Thermodynamic analysis showed that sorption process is spontaneous and endothermic, as indicated by negative ΔG and positive ΔH values. The pseudo-second-order and Langmuir models best describe the sorption kinetics at 293 K (R² > 0.99). Compared to other adsorbents, ODA-IONPs show superior MO removal capacity under a wider pH range. The influence of nanoparticle concentration, pH, and temperature on sorption efficiency is systematically explored, with optimal conditions identified at 10 mg/L ODA-IONPs and pH 6. Furthermore, the feasibility of nanoparticle reusability for sorption purposes is assessed. These findings underscore the potential of ODA-IONPs as efficient sorbents for wastewater treatment and environmental remediation applications.

Keywords


sorption; methyl orange; magnetic nanoparticles; octadecylamine; kinetics; thermodynamics; Fe3O4

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References


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DOI: https://doi.org/10.15826/chimtech.2024.11.3.05

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