In situ  synthesis, structural chemistry and vibrational  spectroscopy of Zn-doped Ca 5 Mg 4 (VO 4 ) 6

Anna S. Tolkacheva; Sergey N. Shkerin; Sofya A. Petrova; Olga M. Fedorova; Svetlana G. Titova; Ivan I. Leonidov

doi:10.15826/chimtech.2022.9.2.01

In situ synthesis, structural chemistry and vibrational spectroscopy of Zn-doped Ca₅Mg₄(VO₄)₆

Anna S. Tolkacheva, Sergey N. Shkerin, Sofya A. Petrova, Olga M. Fedorova, Svetlana G. Titova, Ivan I. Leonidov

Abstract

The phase formation of the solid solution Ca₅Mg_4–xZn_x(VO₄)₆ (0≤x≤4) was studied in situ using differential scanning calorimetry and high-temperature X-Ray powder diffraction (XRPD). XRPD analysis shows the appearance of unavoidable secondary pyrovanadate phases using conventional synthesis methods. The local structure of the solid solution was verified by vibrational spectroscopy. The analysis of the infrared and Raman spectroscopy data allows establishing the main features between vanadate garnets and their isostructural analogs among natural silicates.

Keywords

crystal structure, vibrational spectroscopy, X-ray diffraction, ceramics, differential scanning calorimetry, pyrovanadate, garnet

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DOI: https://doi.org/10.15826/chimtech.2022.9.2.01

Copyright (c) 2021 Anna S. Tolkacheva, Sergey N. Shkerin, Sofya A. Petrova, Olga M. Fedorova, Svetlana G. Titova, Ivan I. Leonidov

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