Surface modification of colloidal silicon dioxide with polyantimonic acid

Fedor A. Yaroshenko; Ekaterina D. Rubtsova; Timofey D. Bodrov; Vladimir A. Burmistrov; Yulia A. Lupitskaya; Damir M. Galimov; Ksenia G. Belova; Veronika E. Epp; Elizaveta S. Karabelnikova; Artem V. Dimitrenko

doi:10.15826/chimtech.9029

Surface modification of colloidal silicon dioxide with polyantimonic acid

Fedor A. Yaroshenko, Ekaterina D. Rubtsova, Timofey D. Bodrov, Vladimir A. Burmistrov, Yulia A. Lupitskaya, Damir M. Galimov, Ksenia G. Belova, Veronika E. Epp, Elizaveta S. Karabelnikova, Artem V. Dimitrenko

Abstract

The study demonstrates the possibility of direct surface modification of colloidal silicon dioxide with polyantimonic acid without preliminary treatment or functionalization of the silica surface. The porosity values, bulk and pycnometric densities were determined for both mechanical mixtures of colloidal silicon dioxide with polyantimonic acid and for colloidal silicon dioxide particles that were surface-modified with polyantimonic acid. Micrographs and particle size distribution curves reveal that surface modification of colloidal silicon dioxide with polyantimonic acid results in formation of nearly monodisperse particles with size of about 100 nm. IR spectroscopy confirmed the formation of chemical bonds between the surface of colloidal silicon dioxide and polyantimonic acid.

Keywords

polyantimonic acid; colloidal silicon dioxide; surface modification; core-shell

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References

Loza SA, Smyshlyaev NA, Korzhov AN, Romanyuk NA. Electrodialysis Concentration of Sulfuric Acid. Chimica Techno Acta. 2021;8(1):20218106. doi:10.15826/chimtech.2021.8.1.06

Stenina IA, Yaroslavtsev AB. Prospects for the Development of Hydrogen Energy. Polymer Membranes for Fuel Cells and Electrolyzers. Membr Membr Technol. 2024;6:15–26. doi:10.1134/S2517751624010050

Prikhno IA, Safronova EY, Yaroslavtsev AB, Wu W. Synthesis and study of hybrid materials based on Nafion membranes, hydrated silica, phosphotungstic acid, and its acid salts. Petroleum Chem. 2014;54(7):556–561. doi:10.1134/S0965544114070093

Chang-Chun Ke, Xiao-Jin Li, Qiang Shen, Shu-Guo Qu, Zhi-Gang Shao, Bao-Lian Yi. Investigation on sulfuric acid sulfonation of in-situ sol–gel derived Nafion/SiO2 composite membrane. Int J Hydrogen Energy. 2011;36(5):3606–3613. doi:10.1016/j.ijhydene.2010.12.030

Lavrova GV, Ponomareva VG, Uvarov NF, et al. Nanocomposite proton conductors containing mesoporous oxides as the promising fuel cell membranes. Russ J Electrochem. 2014;50(7):603–612. doi:10.1134/S1023193514070088

Ponomareva VG, Bagryantseva IN, Shutova ES, et al. Structural transformations and proton conductivity of Me4NHSO4 and nanocomposites Me4NHSO4 - SiO2. Solid State Ionics. 2025;423:116810. doi:10.1016/j.ssi.2025.116810

Stenina IA, Yaroslavtsev AB. Nanomaterials for lithium-ion batteries and hydrogen energy. Pure Appl Chem. 2017;89(8):1185–1194. doi:10.1515/pac-2016-1204

Vdovin GK, Rudenko AO. Antonov BD, et al. Manipulating the grain boundary properties of BaCeO3-based ceramic materials through sintering additives introduction Chimica Techno Acta. 2019;6(2):38–45. doi:10.15826/chimtech.2019.6.2.01

Reza M, Rahmayani RFI, Radiman CL. Effects of Coagulant Bath Temperature Toward Separation Performance and Antifouling Properties of PVDF/CA Membranes for Filtration of Dyes. Chimica Techno Acta. 2024;11(2):202411201. doi:10.15826/chimtech.2024.11.2.01

Lebedeva OV, Sipkina EI. Composite membranes for fuel cells. Izvestiya Vuzov. Prikladnaya Khimiya i Biotekhnologiya. 2023;13(2):172–183. doi:10.21285/2227-2925-2023-13-2-172-183

Kravets LI, Altynov VA, Gainutdinov RV, Shesterikov EV, Kulinich IV, Tverdokhlebov SI. Formation of composite membranes with asymmetry of conductivity by plasma chemical deposition of silicon dioxide nanoparticles. 2023;16(7–8):416–425. doi:10.22184/1993-8578.2023.16.7-8.416.425

Voropaeva EYu, Shalimov AS, Stenina IA, et al. Transport properties of MF-4SK membranes modified with inorganic dopants. Russ J Inorg Chem. 2008;53(10):1536–1541. doi:10.1134/S0036023608100021

Yaroshenko FA, Burmistrov VA. Proton conductivity of polyantimonic acid studied by impedance spectroscopy in the temperature range 370–480 K. Inorg Mater. 2015;51(8):783–787. doi:10.1134/S0020168515080208

Yaroshenko FA, Burmistrov VA. Dielectric losses and proton conductivity of polyantimonic acid membranes. Russ J Electrochem. 2016;52(7):690–693. doi:10.1134/S1023193516070193

Kovalenko LY, Yaroshenko FA, Burmistrov VA, et al. Thermolysis of Hydrated Antimony Pentoxide. Inorg Mater. 2019;55(6):586–592. doi:10.1134/S0020168519060086

Sliesarenko VV, Dudarko OA, Matkovskii AK, et al. Immobilization of phosphomolybdic acid on the surface of mesoporous silica functionalized with alkylammonium groups. Colloid J. 2014;76(3):366–371. doi:10.1134/S1061933X14020124

DOI: https://doi.org/10.15826/chimtech.9029

Copyright (c) 2025 Fedor A. Yaroshenko, Ekaterina D. Rubtsova, Timofey D. Bodrov, Vladimir A. Burmistrov, Yulia A. Lupitskaya, Damir M. Galimov, Ksenia G. Belova, Veronika E. Epp, Elizaveta S. Karabelnikova, Artem V. Dimitrenko

This work is licensed under a Creative Commons Attribution 4.0 International License.

Chimica Techno Acta, 2014–2025
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