Cover Image

Thermal properties of fluoride mixtures near the melting point

Aleksey Rudenko, Alexander Redkin, Evgeniya Il’ina, Svetlana Pershina

Abstract


The thermal diffusivity of LiF-NaF-KF (FLiNaK), NaF-KF and FliNaK-NdF3 mixtures was studied by laser flash method near the melting point. The obtained results demonstrate that the thermal diffusivity of the melts slowly decreases within a certain temperature range. Thermal diffusivity of eutectic FLiNaK and NaF-KF mixtures was found to drop sharply at the temperatures of 30–50 ° below the melting point. These values correspond to the overcooling interval. Thermal conductivity was calculated using the thermal diffusivity heat capacity and density data. Thermal diffusivity of the FliNaK-NdF3 mixture decreases slowly in the phase transition temperature range.

Keywords


thermal diffusivity; heat capacity; melting point; thermal conductivity; fluoride mixtures

Full Text:

PDF

References


Williams D. Additional physical property measurements and assessment of salt compositions proposed for the intermediate heat transfer loop. 2006; ORNL/GEN4/LTR-06-033

Khairulin RA, Abdullaev RN, Stankus SV, et al. Volumetric properties of liquid and solid LiF–KF mixtures. Thermophys Aeromech. 2023;30:747–55. doi:10.1134/S0869864323040133

Palimaka P, Pietrzyk S. Research on the electrical conductivity of fluoride electrolytes NaF–AlF₃ in liquid and solid state. Arch Metall Mater. 2010;35(2):533–38.

Landon G, Ubbelohde A. Melting and crystal structure of cryolite (3NaF, AlF₃). Trans Faraday Soc. 1956;56:647–51.

Rudenko AV, Kataev AA, Tkacheva OY, et al. Electrical conductivities of solid and liquid cryolite systems. Russ Metall. 2019;2:104–7. doi:10.1134/S0036029519020216

Redkin AA, Il’ina EA, Pershina SV, Mushnikov PN, Stankus SV, Agazhanov A, Zaikov YP, Kholkina AS, Artamonov AS. Thermal properties of Li₂BeF₄ near melting point. Thermo. 2022;2(3):107–15. doi:10.3390/thermo2030010

Golyshev VD, Gonik MA, Tsvetovsky VB. Study of thermal conductivity close to the melting point. High Temp High Press. 2003;35–36(2):139–148. doi:10.1068/htjr106

Khokhlov VA, Kodintseva AO, Filatov ES. Anomalous thermal conductivity of crystalline alkali halides close to their melting point. Z Naturforsch A. 1993;48(4):595–98. doi:10.1515/zna-1993-0409

Stankus SV, Savchenko IV. Laser flash method for measurement of liquid metals heat transfer coefficients. Thermophys Aeromech. 2009;16:585–92. doi:10.1134/S0869864309040076

Rudenko AV, Redkin AA, Il’ina EA, Pershina SV, Mushnikov PN, Zaikov YP, Kumkov SI, Liu Y, Shi W. Thermal conductivity of FLiNaK in a molten state. Materials. 2022;15(16):5603. doi:10.3390/ma15165603

Redkin AA, Khudorozhkova AO, Il’ina EA, Pershina SV, Mushnikov PN, Isakov AV, Zaikov YP, Kataev AA, Laptev MV. Density and heat capacity of some molten mixtures in system LiF–BeF₂–UF₄. J Mol Liq. 2021;341:117215. doi:10.1016/j.molliq.2021.117215

Rudenko AV, Redkin AA, Galashev AE, Abramova KA, Rakhmanova OR, Il’ina EA, Pershina SV, Zaikov YP. Thermal properties of NaF–KF and NaF–KF–MgF₂ molten eutectic mixtures: Experiment and simulation. Int J Thermophys. 2024;45:114. doi:10.1007/s10765-024-03335-1

Mushnikov PN, Tkacheva OYu, Voronin VM, Shishkin VYu, Zaikov YP. Investigation of quasi-binary phase diagram FLiNaK–NdF₃. Materials. 2021;14:6428. doi:10.3390/ma14216428

Rogers T, Yoko J, Janz G. Fusion properties and heat capacities of the eutectic LiF–NaF–KF melt. J Chem Eng Data. 1982;27:366–67.

Ubbelohde A. Pre-melting and pre-freezing. Mater Sci Pure Appl Chem. 1961;251–255.

Minchenko VI, Reshetnikova NV, Khokhlov VA, Korzun IV. The influence of pre-melting effect on propagation of ultrasound in eutectic mixtures of lithium, sodium, potassium and cesium chlorides near phase transition crystal–liquid. Rasplavy. 2005;4:41–46.




DOI: https://doi.org/10.15826/chimtech.2025.12.3.03

Copyright (c) 2025 Aleksey Rudenko, Alexander Redkin, Evgeniya Il’ina, Svetlana Pershina

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

Scopus logo WorldCat logo DOAJ logo CAS logo BASE logo eLibrary logo

Chimica Techno Acta, 2014–2025
eISSN 2411-1414
Copyright Notice