Photocatalytic Degradation of Remazol Black B (RBB) Using ZnO/Zeolite and Its Application to Textile Wastewater

Rahmadhani Khairul Baryah; Zilfa Zilfa; Alpan Sofyan Tanjung; Tio Putra Wendari

doi:10.15826/chimtech.10273

Photocatalytic Degradation of Remazol Black B (RBB) Using ZnO/Zeolite and Its Application to Textile Wastewater

Rahmadhani Khairul Baryah, Zilfa Zilfa, Alpan Sofyan Tanjung, Tio Putra Wendari

Abstract

The presence of Remazol Black B (RBB) in water has a negative impact on the environment and living organisms. Photodegradation using ZnO/zeolite is a promising approach for reducing RBB concentration through photocatalytic transformation. This study aims to synthesize ZnO/zeolite composites and evaluate their photocatalytic performance in degrading RBB in both synthetic samples and real textile wastewater. Structural characterization using FTIR, XRD, and SEM-EDX confirmed the successful incorporation of ZnO into the zeolite matrix and the zeolite framework was successfully preserved during the synthesis process. Subsequently, a catalyst dose of 1.0 g and a solution volume of 10 mL were determined using the 30-minute irradiation time as a reference condition, rather than as the overall optimum. Under these conditions, the ZnO/zeolite composite achieved a degradation rate of 98.16% and outperformed both zeolite and ZnO alone. Furthermore, the degradation kinetics of RBB using the ZnO/zeolite composite followed a pseudo-first-order kinetic model with a pseudo-rate constant of 0.0592 min^-1. However, when applied to actual textile wastewater, the degradation efficiency decreased to 32.08%, indicating the influence of the complex wastewater matrix on photocatalytic performance. These findings indicate that the high photocatalytic activity in model solutions does not always reflect real wastewater performance due to its diverse chemical composition.

Keywords

ZnO/zeolite; Remazol Black B; Reactive azo dye; photocatalytic degradation; textile wastewater

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References

G. B. Singh, A. Vinayak, G. Mudgal, and K. K. Kesari, “Azo dye bioremediation: An interdisciplinary path to sustainable fashion,” Environ. Technol. Innov., vol. 36, p. 103832, Nov. 2024, doi:10.1016/j.eti.2024.103832

R. O. Alves de Lima, A. P. Bazo, D. M. F. Salvadori, C. M. Rech, D. de Palma Oliveira, and G. de Aragão Umbuzeiro, “Mutagenic and carcinogenic potential of a textile azo dye processing plant effluent that impacts a drinking water source,” Mutat. Res. Toxicol. Environ. Mutagen., vol. 626, no. 1–2, pp. 53–60, Jan. 2007, doi:10.1016/j.mrgentox.2006.08.002

V. S. Reddy Ramireddy, R. Kurakula, P. Velayudhaperumal Chellam, A. James, and E. D. van Hullebusch, “Systematic computational toxicity analysis of the ozonolytic degraded compounds of azo dyes: Quantitative structure-activity relationship (QSAR) and adverse outcome pathway (AOP) based approach,” Environ. Res., vol. 231, p. 116142, Aug. 2023, doi:10.1016/j.envres.2023.116142

Y. Liu, C. Li, J. Bao, X. Wang, W. Yu, and L. Shao, “Degradation of Azo Dyes with Different Functional Groups in Simulated Wastewater by Electrocoagulation,” Water, vol. 14, no. 1, p. 123, Jan. 2022, doi:10.3390/w14010123

C. Zaharia, C.-P. Musteret, and M.-A. Afrasinei, “The Use of Coagulation–Flocculation for Industrial Colored Wastewater Treatment—(I) The Application of Hybrid Materials,” Appl. Sci., vol. 14, no. 5, p. 2184, Mar. 2024, doi:10.3390/app14052184

R. Godoy Bautista et al., “Enhancing Dye Removal Efficiency Through Sustainable Adsorbent Production from Corncobs (Zea mays L. ssp. amilacea),” Separations, vol. 12, no. 11, p. 322, Nov. 2025, doi:10.3390/separations12110322

B. Dehingia, R. Lahkar, and H. Kalita, “Efficient removal of both cationic and anionic dyes from water using a single rGO/PSS nanocomposite membrane with superior permeability and high aqueous stability,” J. Environ. Chem. Eng., vol. 12, no. 2, p. 112393, Apr. 2024, doi:10.1016/j.jece.2024.112393

S. Ziembowicz and M. Kida, “The Optimization of Advanced Oxidation Processes for the Degradation of Industrial Pollutants,” Sustainability, vol. 17, no. 5, p. 1908, Feb. 2025, doi:10.3390/su17051908

G. A. Ismail and H. Sakai, “Review on effect of different type of dyes on advanced oxidation processes (AOPs) for textile color removal,” Chemosphere, vol. 291, p. 132906, Mar. 2022, doi:10.1016/j.chemosphere.2021.132906

W. Alahmad, F. Hedhili, S. M. Al-Shomar, H. S. Albaqawi, N. A. Al-Shammari, and S. Abdelrahman, “Modeling sustainable photocatalytic degradation of acidic dyes using Jordanian nano-Kaolin–TiO2 and solar energy: Synergetic mechanistic insights,” Heliyon, vol. 10, no. 17, p. e36978, Sep. 2024, doi:10.1016/j.heliyon.2024.e36978

A. Kołodziejczak-Radzimska and T. Jesionowski, “Zinc Oxide—From Synthesis to Application: A Review,” Materials (Basel)., vol. 7, no. 4, pp. 2833–2881, Apr. 2014, doi:10.3390/ma7042833

R. Brayner et al., “ZnO Nanoparticles: Synthesis, Characterization, and Ecotoxicological Studies,” Langmuir, vol. 26, no. 9, pp. 6522–6528, May 2010, doi:10.1021/la100293s

M. R. Ahmad, A. A. Ansari, M. Dhayal, and R. Lv, “Bandgap engineering of ZnO nanomaterials for enhanced electrochemical and photocatalytic efficiency,” Renew. Sustain. Energy Rev., vol. 219, p. 115767, Sep. 2025, doi:10.1016/j.rser.2025.115767

M. Tayebi, A. Tayyebi, Z. Masoumi, and B.-K. Lee, “Photocorrosion suppression and photoelectrochemical (PEC) enhancement of ZnO via hybridization with graphene nanosheets,” Appl. Surf. Sci., vol. 502, p. 144189, Feb. 2020, doi:10.1016/j.apsusc.2019.144189

J. Li, M. Gao, W. Yan, and J. Yu, “Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties,” Chem. Sci., vol. 14, no. 8, pp. 1935–1959, 2023, doi:10.1039/D2SC06010H

K. Guesh, Á. Mayoral, C. Márquez-Álvarez, Y. Chebude, and I. Díaz, “Enhanced photocatalytic activity of TiO2 supported on zeolites tested in real wastewaters from the textile industry of Ethiopia,” Microporous Mesoporous Mater., vol. 225, pp. 88–97, May 2016, doi:10.1016/j.micromeso.2015.12.001

Z. Zilfa, R. Yeni Stiadi, and A. Adril, “Utilization of Natural Zeolite Clipnotilolit-Ca as a Support of ZnO Catalyst for Congo-Red Degradation and Congo-Red Waste Applications with Photolysis,” Orient. J. Chem., vol. 34, no. 2, pp. 887–893, Apr. 2018, doi:10.13005/ojc/340237

Z. Zilfa, R. Zein, and T. N. Rahmi, “Pemanfaatan Zeolit Alam Clinoptilolite-Ca sebagai Pendukung Katalis ZnO untuk Mendegradasi Zat warna Methyl Orange dengan Metoda Fotolisis,” J. of Research and Education Chemistry, vol. 5, no. 1, pp. 24–37, April 2023, doi:10.25299/jrec.2023.vol5(1).12505

E. Altintig and O. Kabadayi, “Clinoptilolite-Supported ZnO and TiO2 Composites for High-Efficiency Adsorption of Methylene Blue,” Processes, vol. 14, no. 3, p. 575, Feb. 2026, doi:10.3390/pr14030575

O. Korkuna, R. Leboda, J. Skubiszewska-Zie¸ba, T. Vrublevs’ka, V. M. Gun’ko, and J. Ryczkowski, “Structural and physicochemical properties of natural zeolites: clinoptilolite and mordenite,” Microporous Mesoporous Mater., vol. 87, no. 3, pp. 243–254, Jan. 2006, doi:10.1016/j.micromeso.2005.08.002

M. R. Abukhadra, M. G. Basyouny, A. M. El-Sherbeeny, and M. A. El-Meligy, “Insight into the green doping of clinoptilolite with Na+ ions (Na+/Clino) as nanocatalyst in the conversion of palm oil into biodiesel; optimization and mechanism,” Nanotechnology, vol. 32, p. 155702, 2021, doi:10.1088/1361-6528/abd7b0

C. Auepattana-aumrung, V. Márquez, S. Wannakao, B. Jongsomjit, J. Panpranot, and P. Praserthdam, “Role of Al in Na-ZSM-5 zeolite structure on catalyst stability in butene cracking reaction,” Sci. Rep., vol. 10, no. 1, p. 13643, Aug. 2020, doi:10.1038/s41598-020-70568-z

D. Sarkar, J. Pramanik, S. Samajdar, M. Biswas, and S. Ghosh, “Charge carrier dynamics in semiconductor–cocatalyst interfaces: influence on photocatalytic activities,” RSC Appl. Interfaces, vol. 2, no. 3, pp. 573–598, 2025, doi:10.1039/D5LF00044K

A. A. Alswata, M. Bin Ahmad, N. M. Al-Hada, H. M. Kamari, M. Z. Bin Hussein, and N. A. Ibrahim, “Preparation of Zeolite/Zinc Oxide Nanocomposites for toxic metals removal from water,” Results Phys., vol. 7, pp. 723–731, 2017, doi:10.1016/j.rinp.2017.01.036

M. Bahrami and A. Nezamzadeh-Ejhieh, “Effect of the supported ZnO on clinoptilolite nano-particles in the photodecolorization of semi-real sample bromothymol blue aqueous solution,” Mater. Sci. Semicond. Process., vol. 30, pp. 275–284, Feb. 2015, doi:10.1016/j.mssp.2014.10.006

N. P. Diantariani, I. Kartini, A. Kuncaka, and E. T. Wahyuni, “ZnO INCORPORATED ON NATURAL ZEOLITE FOR PHOTODEGRADATION OF METHYLENE BLUE,” Rasayan J. Chem., vol. 13, no. 01, pp. 747–756, 2020, doi:10.31788/RJC.2020.1315597

E. L. Uzunova and H. Mikosch, “Cation site preference in zeolite clinoptilolite: A density functional study,” Microporous Mesoporous Mater., vol. 177, pp. 113–119, Sep. 2013, doi:10.1016/j.micromeso.2013.05.003

A. Nezamzadeh-Ejhieh and F. Khodabakhshi-Chermahini, “Incorporated ZnO onto nano clinoptilolite particles as the active centers in the photodegradation of phenylhydrazine,” J. Ind. Eng. Chem., vol. 20, no. 2, pp. 695–704, Mar. 2014, doi:10.1016/j.jiec.2013.05.035

L. K. Munguti, F. B. Dejene, and D. K. Muthee, “High photodegradation performance of ZnO nanoparticles supported on porous Zeolite Na-A: Effects of ZnO loading,” Mater. Chem. Phys., vol. 295, p. 127063, Feb. 2023, doi:10.1016/j.matchemphys.2022.127063

E. T. Wahyuni, N. P. Diantariani, I. Kartini, and A. Kuncaka, “Enhancement of the photostability and visible photoactivity of ZnO photocatalyst used for reduction of Cr(VI) ions,” Results Eng., vol. 13, p. 100351, Mar. 2022, doi:10.1016/j.rineng.2022.100351

M. Haghighi, F. Rahmani, R. Dehghani, A. M. Tehrani, and M. B. Miranzadeh, “Photocatalytic reduction of Cr (VI) in aqueous solution over ZnO/HZSM-5 nanocomposite: optimization of ZnO loading and process conditions,” Desalin. Water Treat., vol. 58, pp. 168–180, Jan. 2017, doi:10.5004/dwt.2017.0145

A. Olad, M. Khatamian, and B. Naseri, “Removal of toxic hexavalent chromium by polyaniline modified clinoptilolite nanoparticles,” J. Iran. Chem. Soc., vol. 8, no. S1, pp. S141–S151, Feb. 2011, doi:10.1007/BF03254291

L. Wang, C. Han, M. N. Nadagouda, and D. D. Dionysiou, “An innovative zinc oxide-coated zeolite adsorbent for removal of humic acid,” J. Hazard. Mater., vol. 313, pp. 283–290, Aug. 2016, doi:10.1016/j.jhazmat.2016.03.070

A. R. Sowunmi et al., “Dataset on the comparison of synthesized and commercial zeolites for potential solar adsorption refrigerating system,” Data Br., vol. 20, pp. 90–95, Oct. 2018, doi:10.1016/j.dib.2018.07.040

C. Liu et al., “CO2 capture using low silica X zeolite synthesized from low-grade coal gangue via a two-step activation method,” J. Environ. Chem. Eng., vol. 12, no. 2, p. 112074, Apr. 2024, doi:10.1016/j.jece.2024.112074

R. Mariselvam, A. J. A. Ranjitsingh, P. Mosae Selvakumar, A. A. Alarfaj, and M. A. Munusamy, “Spectral Studies of UV and Solar Photocatalytic Degradation of AZO Dye and Textile Dye Effluents Using Green Synthesized Silver Nanoparticles,” Bioinorg. Chem. Appl., vol. 2016, pp. 1–8, 2016, doi:10.1155/2016/8629178

W. Zhang, Y. Ji, N. Shen, Q. Jia, and W. Chang, “Study of the photodegradation of 2-chlorobenzoic acid by TiO2 and the effects of eutrophicated water on the reaction,” Saudi J. Biol. Sci., vol. 28, no. 1, pp. 163–169, Jan. 2021, doi:10.1016/j.sjbs.2020.09.029

S. Chong, A. R. Aziz, S. Harun, and H. Arof, “Temperature Compensation in Determining of Remazol Black B Concentrations Using Plastic Optical Fiber Based Sensor,” Sensors, vol. 14, no. 9, pp. 15836–15848, Aug. 2014, doi:10.3390/s140915836.

E. Salah Elbanna, A. A. Farghali, M. H. Khedr, and M. Taha, “Nano clinoptilolite zeolite as a sustainable adsorbent for dyes removal: Adsorption and computational mechanistic studies,” J. Mol. Liq., vol. 409, p. 125538, Sep. 2024, doi:10.1016/j.molliq.2024.125538

M. Rakanović et al., “Zeolites as Adsorbents and Photocatalysts for Removal of Dyes from the Aqueous Environment,” Molecules, vol. 27, no. 19, p. 6582, Oct. 2022, doi:10.3390/molecules27196582

K. Lee, H. Ku, and D. Pak, “OH radical generation in a photocatalytic reactor using TiO2 nanotube plates,” Chemosphere, vol. 149, pp. 114–120, Apr. 2016, doi:10.1016/j.chemosphere.2016.01.103

A. R. Bhapkar and S. Bhame, “A review on ZnO and its modifications for photocatalytic degradation of prominent textile effluents: Synthesis, mechanisms, and future directions,” J. Environ. Chem. Eng., vol. 12, no. 3, p. 112553, Jun. 2024, doi:10.1016/j.jece.2024.112553

V. V. Aherkar et al., “Photocatalytic dye degradation efficacy and antimicrobial potency of zinc oxide nanoparticles synthesized via sol-gel method,” Next Mater., vol. 9, p. 100972, Oct. 2025, doi:10.1016/j.nxmate.2025.100972

C. Mrabet, R. Jaballah, N. Mahdhi, A. Boukhachem, and M. Amlouk, “CuO-ZnO nanocomposites-based thin films: Characterization, physical properties and sunlight photocatalytic degradation of organic pollutants,” J. Alloys Compd., vol. 968, p. 172252, Dec. 2023, doi:10.1016/j.jallcom.2023.172252

H. V. Lutze, N. Kerlin, and T. C. Schmidt, “Sulfate radical-based water treatment in presence of chloride: Formation of chlorate, inter-conversion of sulfate radicals into hydroxyl radicals and influence of bicarbonate,” Water Res., vol. 72, pp. 349–360, Apr. 2015, doi:10.1016/j.watres.2014.10.006

N. Zamani-Faradanbeh and A. Nezamzadeh-Ejhieh, “Synergistic effects of the zeolite support and semiconductor coupling in the enhanced photodegradation kinetics of malachite green and Congo red aqueous mixture,” Results Chem., vol. 21, p. 103053, Mar. 2026, doi:10.1016/j.rechem.2026.103053

G. Petcu et al., “Effects of Aluminosilicate Gel Treatment and TiO2 Loading on Photocatalytic Properties of Au–TiO2/Zeolite Y,” Gels, vol. 9, no. 6, p. 503, Jun. 2023, doi:10.3390/gels9060503

DOI: https://doi.org/10.15826/chimtech.10273

Copyright (c) 2026 Rahmadhani Khairul Baryah, Zilfa, Alpan Sofyan Tanjung, Tio Putra Wendari

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